Can I Airplay video to my Apple TV and sound to this?

In a situation where I had my mac, these speakers and an Apple TV connected to the same network and, say, I found an iPlayer video I wanted to watch, would I be able to stream video (through airplay mirroring) to the Apple TV but send sound simultaneously to the A5?

Additionally, when using the Apple TV as a standalone unit, would it be possible to play sound through these?

Bowers & Wilkins A5 AirPlay Wireless Music System

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